Shape memory in the topcoat
PPF is three layers: a self-healing topcoat, a TPU elastomer core, and a pressure-sensitive adhesive. Healing happens in the top 15–25μm. That coating is a cross-linked polymer whose chains are tethered by elastic anchor points, so a scratch displaces and stretches the chains rather than severing them.
Raise the temperature above the transition point — typically 40–60°C — and the chains regain mobility and snap back to their lowest-energy arrangement. Visually, the scratch vanishes. The cycle repeats as long as the topcoat has not been cut through.